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Gibbs Free Energy Spontaneity Criterion

吉布斯自由能判据与反应自发性

ΔG=ΔH−TΔS(ΔG<0⟹Spontaneous)

Theoretical Identity Description:

Determines the thermodynamic spontaneity of a chemical reaction at constant T and P. Spontaneous when ΔG < 0, at equilibrium when ΔG = 0.

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Rigorous Derivation Tree

2 Logical Steps
Step 1check_circleValid Deduction
ΔG=ΔH−TΔS(ΔG<0⟹Spontaneous)

Foundational identity statement defined under standard mathematical conditions.

Step 2check_circleValid Deduction
ΔG=ΔH−TΔS(ΔG<0)

Targeted algebraic evaluation and parameter substitution.

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CSCA Exam Triggers & Traps

High-Yield Exam Focus
psychologyProblem Pattern Recognition

Use for predicting spontaneous temperature ranges for endothermic reactions with gas production.

errorCommon Examination Pitfalls

Thermodynamic spontaneity (ΔG < 0) means the reaction is energetically feasible, but does NOT guarantee a fast kinetic rate.

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